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Beilstein J. Org. Chem. 2021, 17, 2657–2662, doi:10.3762/bjoc.17.179
Graphical Abstract
Scheme 1: A: Synthesis of (Z)-β-enamido triflates and subsequent stereoselective cross-coupling reactions. B:...
Scheme 2: Substrate scope of the Suzuki coupling leading to enamides 2 and 3. aRatio determined by 19F NMR; b...
Scheme 3: Proposed mechanisms for the formed Suzuki coupling retention products 2 and inversion products 3.